Issue 22, 2010

Versatile routes to selenoether functionalised tertiary phosphines

Abstract

New selenoether functionalised tertiary phosphines, based on aryl (2a, 2b) or alkyl (4) backbones, have been synthesised and characterised. P,Se-chelation has been achieved upon complexation to square-planar PtII (3a) or PdII (3b) metal centres. For 3a and 3b, weak non-covalent M⋯Se contacts were established using single crystal X-ray crystallography.

Graphical abstract: Versatile routes to selenoether functionalised tertiary phosphines

Supplementary files

Article information

Article type
Communication
Submitted
18 Feb 2010
Accepted
09 Apr 2010
First published
19 Apr 2010

Dalton Trans., 2010,39, 5216-5218

Versatile routes to selenoether functionalised tertiary phosphines

T. J. Cunningham, M. R. J. Elsegood, P. F. Kelly, M. B. Smith and P. M. Staniland, Dalton Trans., 2010, 39, 5216 DOI: 10.1039/C0DT00004C

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