A double-walled triangular metal–organic macrocycle based on a [Cu2(COO)4] square paddle-wheel secondary building unit

Xiaokai Song; Xinfang Liu; Minhak Oh; Myoung Soo Lah

doi:10.1039/C0DT00185F

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A double-walled triangular metal–organic macrocycle based on a [Cu₂(COO)₄] square paddle-wheel secondary building unit†

Xiaokai Song,^a Xinfang Liu,^a Minhak Oh^b and Myoung Soo Lah*^b

Author affiliations

* Corresponding authors

^a Department of Chemistry and Applied Chemistry, Hanyang University, Ansan, Kyunggi-do, Korea

^b Interdisciplinary School of Green Energy, Ulsan National Institute of Science & Technology, Ulsan, Korea
E-mail: mslah@unist.ac.kr
Fax: +82 52 217 2909
Tel: +82 52 217 2931

Abstract

A metal–organic macrocycle (MOM), [(Cu₂)₃L₆(DMF)₂(H₂O)₄], was prepared using a long and “pseudo-rigid” dicarboxylic acid, 1,4-bis(3-carboxylphenylethynyl)benzene (H₂L), with some rotational flexibility, where the MOM has a double-walled triangular geometry with three Cu paddle-wheel secondary building units (SBUs) doubly connected by the ligands in a cis-conformation.

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Article information

DOI: https://doi.org/10.1039/C0DT00185F
Article type: Communication
Submitted: 23 Mar 2010
Accepted: 24 May 2010
First published: 07 Jun 2010

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Dalton Trans., 2010,39, 6178-6180

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A double-walled triangular metal–organic macrocycle based on a [Cu₂(COO)₄] square paddle-wheel secondary building unit

X. Song, X. Liu, M. Oh and M. S. Lah, Dalton Trans., 2010, 39, 6178 DOI: 10.1039/C0DT00185F

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Dalton Transactions