Issue 28, 2010
From the journal:

Dalton Transactions

Yttrium bisphosphonate STA-13: A racemic phosphonate metal organic framework with permanent microporosity†

Michael T. Wharmby,a   Stuart R. Miller,a   John A. Groves,a   Irene Margiolaki,b   Sharon E. Ashbrooka  and  Paul A. Wright*a  

* Corresponding authors

a School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, Fife, UK
E-mail: paw2@st-andrews.ac.uk
Fax: 01334 463808
Tel: 01334 463793

b European Synchrotron Radiation Facility, Grenoble, France

Abstract

Crystallisation of yttrium and other trivalent metal cations of similar radius with racemic N,N′-2-methylpiperazinebis(methylene phosphonic acid) gives a small pore bisphosphonate metal–organic framework solid displaying coordinative and hydrogen bonding and permanent porosity.

Graphical abstract: Yttrium bisphosphonate STA-13: A racemic phosphonate metal organic framework with permanent microporosity

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Article information

DOI
https://doi.org/10.1039/C0DT00233J
Article type
Communication
Submitted
31 Mar 2010
Accepted
04 Jun 2010
First published
21 Jun 2010

Dalton Trans., 2010,39, 6389-6391

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Yttrium bisphosphonate STA-13: A racemic phosphonate metal organic framework with permanent microporosity

M. T. Wharmby, S. R. Miller, J. A. Groves, I. Margiolaki, S. E. Ashbrook and P. A. Wright, Dalton Trans., 2010, 39, 6389 DOI: 10.1039/C0DT00233J

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