Issue 44, 2010
From the journal:

Dalton Transactions

Chelated orthoborate ionic liquid as a reactant for the synthesis of a new cobalt borophosphate containing extra-large 16-ring channels†

Miao Yang,*a   Feifei Xu,a   Qingshan Liu,a   Peifang Yan,a   Xiumei Liu,a   Chang Wanga  and  Urs Welz-Biermann*a  

* Corresponding authors

a China Ionic Liquid Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Science, Zhongshan Road 457, Dalian 116023, China
E-mail: yangmiao@dicp.ac.cn, uwb@dicp.ac.cn
Fax: 86 0411 84379992
Tel: 86 0411 84379167

Abstract

1-Ethyl-3-methylimidazolium bis(oxalato)borate ([Emim][BOB]), a room-temperature ionic liquid, has been prepared and used for the first time to develop new borate-containing material. A new open-framework cobalt borophosphate, (NH4)7Co4(H2O)[B2P4O15(OH)2]2[H2PO4][HPO4], with peanut shaped extra-large 16-ring channels has been obtained.

Graphical abstract: Chelated orthoborate ionic liquid as a reactant for the synthesis of a new cobalt borophosphate containing extra-large 16-ring channels

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Article information

DOI
https://doi.org/10.1039/C0DT00368A
Article type
Communication
Submitted
26 Apr 2010
Accepted
11 Aug 2010
First published
09 Sep 2010

Dalton Trans., 2010,39, 10571-10573

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Chelated orthoborate ionic liquid as a reactant for the synthesis of a new cobalt borophosphate containing extra-large 16-ring channels

M. Yang, F. Xu, Q. Liu, P. Yan, X. Liu, C. Wang and U. Welz-Biermann, Dalton Trans., 2010, 39, 10571 DOI: 10.1039/C0DT00368A

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