Issue 27, 2010
From the journal:

Dalton Transactions

Facile dihydrogen release from phosphino-borinate ester Lewis pairs†

Andy M. Chapman,a   Mairi F. Haddow,a   Jonathan P. H. Ortona  and  Duncan F. Wass*a  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK
E-mail: duncan.wass@bristol.ac.uk

Abstract

New phosphino-borinate ester Lewis pairs of the type tBu2PCH2C(R)2OB(C6F5)2 (R = Me or CF3) are synthesised from the corresponding phosphino-alcohol and HB(C6F5)2. Dihydrogen release from the zwitterionic tBu2PHCH2C(R)2OBH(C6F5)2 is facile.

Graphical abstract: Facile dihydrogen release from phosphino-borinate ester Lewis pairs

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Article information

DOI
https://doi.org/10.1039/C0DT00513D
Article type
Communication
Submitted
02 Feb 2010
Accepted
21 May 2010
First published
14 Jun 2010

Dalton Trans., 2010,39, 6184-6186

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Facile dihydrogen release from phosphino-borinate ester Lewis pairs

A. M. Chapman, M. F. Haddow, J. P. H. Orton and D. F. Wass, Dalton Trans., 2010, 39, 6184 DOI: 10.1039/C0DT00513D

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