Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)2/HPMoV/O2 system

Yasushi Obora; Yoshihisa Okabe; Yasutaka Ishii

doi:10.1039/C0OB00176G

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Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)₂/HPMoV/O₂ system†

Yasushi Obora,*^a Yoshihisa Okabe^a and Yasutaka Ishii*^b

Author affiliations

* Corresponding authors

^a Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, High Technology Research Center, Kansai University, Suita, Osaka, Japan
E-mail: obora@kansai-u.ac.jp
Fax: +81-6-6339-4026
Tel: +81-6-6368-0876

^b ORDIST, Kansai University, Suita, Osaka, Japan
E-mail: r091001@kansai-u.ac.jp

Abstract

A facile direct synthesis of cinnamonitriles from acrylonitriles and benzenes is successfully achieved by using Pd(OAc)₂/HPMoV/O₂ catalyst system via the direct C–H bond activation of benzenes using molecular oxygen as a terminal oxidant.

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Supplementary files

Figure S1, Tables, experimental procedures, spectra data, and GC and GC-MS spectra of the products PDF (14260K)

Article information

DOI: https://doi.org/10.1039/C0OB00176G
Article type: Communication
Submitted: 27 May 2010
Accepted: 07 Jul 2010
First published: 23 Jul 2010

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Org. Biomol. Chem., 2010,8, 4071-4073

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Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)₂/HPMoV/O₂ system

Y. Obora, Y. Okabe and Y. Ishii, Org. Biomol. Chem., 2010, 8, 4071 DOI: 10.1039/C0OB00176G

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Organic & Biomolecular Chemistry