High-nuclearity, mixed-valence Mn17, Mn18 and {Mn62}n complexes from the use of triethanolamine

Theocharis C. Stamatatos; Dolos Foguet-Albiol; Wolfgang Wernsdorfer; Khalil A. Abboud; George Christou

doi:10.1039/C0CC01701A

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High-nuclearity, mixed-valence Mn₁₇, Mn₁₈ and {Mn₆₂}_n complexes from the use of triethanolamine†

Theocharis C. Stamatatos,‡*^a Dolos Foguet-Albiol,^a Wolfgang Wernsdorfer,^b Khalil A. Abboud^a and George Christou*^a

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* Corresponding authors

^a Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA

^b Institut Néel, CNRS & Université J. Fourier, BP-166, Grenoble, Cedex 9, France

Abstract

The use of both azide and triethanolamine, with or without the presence of carboxylate groups, has provided new Mn₁₇, Mn₁₈ and {Mn₆₂}_n complexes with aesthetically-pleasing cage, layered, and linked-chain-type structures; two are also new single-molecule magnets.

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Article information

DOI: https://doi.org/10.1039/C0CC01701A
Article type: Communication
Submitted: 02 Jun 2010
Accepted: 16 Jul 2010
First published: 25 Aug 2010

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Chem. Commun., 2011,47, 274-276

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High-nuclearity, mixed-valence Mn₁₇, Mn₁₈ and {Mn₆₂}_n complexes from the use of triethanolamine

T. C. Stamatatos, D. Foguet-Albiol, W. Wernsdorfer, K. A. Abboud and G. Christou, Chem. Commun., 2011, 47, 274 DOI: 10.1039/C0CC01701A

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