Issue 1, 2011
From the journal:

Chemical Communications

Desymmetrizations of meso-tert-norbornenols by rhodium(i)-catalyzed enantioselective retro-allylations†‡

Michael Waibela  and  Nicolai Cramer*a  

* Corresponding authors

a Laboratory of Organic Chemistry, ETH Zurich, HCI H 304, Wolfgang-Pauli-Strasse 10, 8093 Zurich, Switzerland
E-mail: nicolai.cramer@org.chem.ethz.ch
Fax: +41 44 632 1328
Tel: +41 44 632 6412

Abstract

Rhodium-catalyzed desymmetrizations of meso-tert-norbornenols by retro-allylations generate allyl-rhodium species that allow for a rich and diverse downstream reactivity.

Graphical abstract: Desymmetrizations of meso-tert-norbornenols by rhodium(i)-catalyzed enantioselective retro-allylations

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Article information

DOI
https://doi.org/10.1039/C0CC01950J
Article type
Communication
Submitted
18 Jun 2010
Accepted
04 Aug 2010
First published
31 Aug 2010

Chem. Commun., 2011,47, 346-348

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Desymmetrizations of meso-tert-norbornenols by rhodium(I)-catalyzed enantioselective retro-allylations

M. Waibel and N. Cramer, Chem. Commun., 2011, 47, 346 DOI: 10.1039/C0CC01950J

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