High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination framework†‡
Abstract
A bimetallic pillared-layer coordination framework {[Mn3(bipy)3(H2O)4][Cr(CN)6]2·2(bipy)·4(H2O)}n has been constructed using a cyanometallate anion ([Cr(CN)6]3−) and an organic linker (