Issue 3, 2011
From the journal:

Chemical Communications

Palladium catalyzed carboxylation of allylstannanes and boranes using CO2†

Jianguo Wua  and  Nilay Hazari*a  

* Corresponding authors

a The Department of Chemistry, Yale University, PO Box 208107, New Haven, Connecticut, USA
E-mail: nilay.hazari@yale.edu
Fax: +1 203 432 6144
Tel: +1 203 432 0885

Abstract

A family of well-defined (η3-allyl)Pd(L)(carboxylate) (L = PR3 or NHC) complexes are by far the most efficient catalysts reported to date for the catalytic carboxylation of allylstannanes into allylcarboxylates using CO2. The substrate scope of this reaction is extended to both substituted allylstannanes and allylboranes.

Graphical abstract: Palladium catalyzed carboxylation of allylstannanes and boranes using CO2

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Article information

DOI
https://doi.org/10.1039/C0CC03191G
Article type
Communication
Submitted
11 Aug 2010
Accepted
27 Oct 2010
First published
15 Nov 2010

Chem. Commun., 2011,47, 1069-1071

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Palladium catalyzed carboxylation of allylstannanes and boranes using CO2

J. Wu and N. Hazari, Chem. Commun., 2011, 47, 1069 DOI: 10.1039/C0CC03191G

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