Issue 13, 2011
From the journal:

Chemical Communications

14N and 45Sc NMR study of trimetallic nitride cluster (M3N)6+ dynamics inside a icosahedral C80 cage†‡

Wujun Fu,a   Xuelei Wang,a   Hugo Azuremendi,a   Jianyuan Zhanga  and  Harry C. Dorn*a  

* Corresponding authors

a Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, USA
E-mail: hdorn@vt.edu
Fax: +1(1)540 231 3255
Tel: +1(1)540 231 5953

Abstract

The dynamics of the trimetallic nitride (M3N)6+ (M = Sc, Y and Lu) clusters in the Ih-(C80)6− cage have been studied by 14N and 45Sc nuclear magnetic resonance. These NMR studies suggest that the motional barrier of (M3N)6+ is related to the cluster size and increases in the series (Sc, Y, and Lu).

Graphical abstract: 14N and 45Sc NMR study of trimetallic nitride cluster (M3N)6+ dynamics inside a icosahedral C80 cage

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Article information

DOI
https://doi.org/10.1039/C0CC03893H
Article type
Communication
Submitted
15 Sep 2010
Accepted
26 Jan 2011
First published
17 Feb 2011

Chem. Commun., 2011,47, 3858-3860

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14N and 45Sc NMR study of trimetallic nitride cluster (M3N)6+ dynamics inside a icosahedral C80 cage

W. Fu, X. Wang, H. Azuremendi, J. Zhang and H. C. Dorn, Chem. Commun., 2011, 47, 3858 DOI: 10.1039/C0CC03893H

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