Exploring the reactions of CO2 with PCP supported nickel complexes

Timothy J. Schmeier; Nilay Hazari; Christopher D. Incarvito; Jevgenij A. Raskatov

doi:10.1039/C0CC03898A

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Exploring the reactions of CO₂ with PCP supported nickel complexes†

Timothy J. Schmeier,^a Nilay Hazari,*^a Christopher D. Incarvito^a and Jevgenij A. Raskatov^b

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* Corresponding authors

^a The Department of Chemistry, Yale University, PO Box 208107, New Haven, Connecticut, USA
E-mail: nilay.hazari@yale.edu
Fax: +1 203 432 6144
Tel: +1 203 432 0885

^b Organisch-Chemisches Institut der Universität Heidelberg, Im Neuenheimer Feld 273, D-69120 Heidelberg, Germany

Abstract

The reactions of PCP supported Ni hydride, methyl and allyl species with CO₂ to generate Ni carboxylates are described. Computational studies suggest that all three reactions follow different pathways.

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Article information

DOI: https://doi.org/10.1039/C0CC03898A
Article type: Communication
Submitted: 16 Sep 2010
Accepted: 21 Nov 2010
First published: 14 Dec 2010

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Chem. Commun., 2011,47, 1824-1826

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Exploring the reactions of CO₂ with PCP supported nickel complexes

T. J. Schmeier, N. Hazari, C. D. Incarvito and J. A. Raskatov, Chem. Commun., 2011, 47, 1824 DOI: 10.1039/C0CC03898A

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