Issue 3, 2011
From the journal:

Chemical Communications

Linking [2]rotaxane wheels to create a new type of metal organic rotaxane framework†

Darren J. Mercer,a   V. Nicholas Vukotica  and  Stephen J. Loeb*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Windsor, Windsor, Canada
E-mail: loeb@uwindsor.ca
Fax: +1 519 973 7098
Tel: +1 519 253 3000

Abstract

Three new [2]rotaxanes with aromatic nitrogen donors appended to the crown ether wheel have been synthesized and used as ligands to coordinate Cd(II) ions. One of these yields a new type of 2-periodic, metal organic rotaxane framework in which the wheel rather than the axle is used to link the metal nodes.

Graphical abstract: Linking [2]rotaxane wheels to create a new type of metal organic rotaxane framework

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Article information

DOI
https://doi.org/10.1039/C0CC04139D
Article type
Communication
Submitted
29 Sep 2010
Accepted
22 Oct 2010
First published
12 Nov 2010

Chem. Commun., 2011,47, 896-898

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Linking [2]rotaxane wheels to create a new type of metal organic rotaxane framework

D. J. Mercer, V. N. Vukotic and S. J. Loeb, Chem. Commun., 2011, 47, 896 DOI: 10.1039/C0CC04139D

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