Issue 6, 2011
From the journal:

Chemical Communications

Time-resolved UV-visible spectroelectrochemistry using transparent 3D-mesoporous nanocrystalline ITO electrodes†

Christophe Renault,a   Kenneth D. Harris,b   Michael J. Brett,bc   Véronique Balland*a  and  Benoît Limoges*a  

* Corresponding authors

a Laboratoire d'Electrochimie Moléculaire, Université Paris Diderot, UMR CNRS 7591, 15, rue Jean-Antoine de Baïf, 75205 Paris Cedex 13, France
E-mail: veronique.balland@univ-paris-diderot.fr, limoges@univ-paris-diderot.fr
Tel: +33 157278789

b National Research Council (NRC), National Institute for Nanotechnology (NINT), Edmonton, Alberta, Canada

c Electrical and Computer Engineering, University of Alberta, Edmonton, Alberta, Canada

Abstract

Efficient and rapid adsorption of microperoxidase 11 within a highly porous ITO thin film (200 nm) prepared by glancing angle deposition was achieved. Adsorbed redox molecules were reversibly and rapidly reduced throughout the 3D-conductive matrix in ca. 50 ms, allowing the heterogeneous electron transfer rate to be determined by derivative cyclic voltabsorptometry.

Graphical abstract: Time-resolved UV-visible spectroelectrochemistry using transparent 3D-mesoporous nanocrystalline ITO electrodes

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Article information

DOI
https://doi.org/10.1039/C0CC04154H
Article type
Communication
Submitted
30 Sep 2010
Accepted
15 Nov 2010
First published
03 Dec 2010

Chem. Commun., 2011,47, 1863-1865

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Time-resolved UV-visible spectroelectrochemistry using transparent 3D-mesoporous nanocrystalline ITO electrodes

C. Renault, K. D. Harris, M. J. Brett, V. Balland and B. Limoges, Chem. Commun., 2011, 47, 1863 DOI: 10.1039/C0CC04154H

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