Issue 2, 2011
From the journal:

Chemical Communications

New synthesis of meso-free-[14]triphyrin(2.1.1) by McMurry coupling and its derivatization to Mn(i) and Re(i) complexes†

Daiki Kuzuhara,a   Hiroko Yamada,*a   ZhaoLi Xue,a   Tetsuo Okujima,a   Shigeki Mori,b   Zhen Shenc  and  Hidemitsu Unoa  

* Corresponding authors

a Graduate School of Science and Engineering, Ehime University, 2–5, Bunkyo-cho, Matsuyama, Japan
E-mail: yamada@chem.sci.ehime-u.ac.jp
Fax: +81 89-927-9613
Tel: +81 89-927-9613

b Department of Molecular Science, Integrated Center for Sciences, Ehime University, Matsuyama 790-8577, Japan

c State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Abstract

The metal-free and meso-free [14]triphyrin(2.1.1) compound was successfully prepared based on the intramolecular McMurry coupling reaction of diformyl-tripyrrane in 16% yield, and was converted to the bowl-shaped Mn(I)(TriP)(CO)3 and Re(I)(TriP)(CO)3.

Graphical abstract: New synthesis of meso-free-[14]triphyrin(2.1.1) by McMurry coupling and its derivatization to Mn(i) and Re(i) complexes

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Article information

DOI
https://doi.org/10.1039/C0CC04286B
Article type
Communication
Submitted
08 Oct 2010
Accepted
29 Oct 2010
First published
16 Nov 2010

Chem. Commun., 2011,47, 722-724

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New synthesis of meso-free-[14]triphyrin(2.1.1) by McMurry coupling and its derivatization to Mn(I) and Re(I) complexes

D. Kuzuhara, H. Yamada, Z. Xue, T. Okujima, S. Mori, Z. Shen and H. Uno, Chem. Commun., 2011, 47, 722 DOI: 10.1039/C0CC04286B

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