Crystal structures, EPR and magnetic properties of 2-ClC6H4CNSSN˙ and 2,5-Cl2C6H3CNSSN˙

Antonio Alberola; Emma Carter; Christos P. Constantinides; Dana J. Eisler; Damien M. Murphy; Jeremy M. Rawson

doi:10.1039/C0CC04296J

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Crystal structures, EPR and magnetic properties of 2-ClC₆H₄CNSSN˙ and 2,5-Cl₂C₆H₃CNSSN˙†

Antonio Alberola,^a Emma Carter,^b Christos P. Constantinides,^c Dana J. Eisler,^c Damien M. Murphy^b and Jeremy M. Rawson*^cd

Author affiliations

* Corresponding authors

^a Dep. De Quimica Fisica I Analitica-Quimica Fisica, Universitat Jaume I, Av. De Vicent Sos Baynat s/n, E-12071 Castello de la Plana, Spain

^b The School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK

^c Department of Chemistry, The University of Cambridge, Lensfield Road, Cambridge, UK

^d Dept of Chemistry and Biochemistry, The University of Windsor, 401 Sunset Av., Windsor, ON, Canada
E-mail: jmrawson@uwindsor.ca

Abstract

The β-sheet structure associated with chlorinated aromatics (d_Cl_⋯_Cl ≈ 4.0 Å) has been implemented to drive formation of π-stacked structures of dithiadiazolyl radicals. Both title compounds exhibit an increase in paramagnetism above 150 K but solid-state EPR studies indicate that the origin of the paramagnetism in these two systems is different.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C0CC04296J
Article type: Communication
Submitted: 08 Oct 2010
Accepted: 14 Dec 2010
First published: 12 Jan 2011

Download Citation

Chem. Commun., 2011,47, 2532-2534

Permissions

Request permissions

Crystal structures, EPR and magnetic properties of 2-ClC₆H₄CNSSN˙ and 2,5-Cl₂C₆H₃CNSSN˙

A. Alberola, E. Carter, C. P. Constantinides, D. J. Eisler, D. M. Murphy and J. M. Rawson, Chem. Commun., 2011, 47, 2532 DOI: 10.1039/C0CC04296J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications