Issue 13, 2011
From the journal:

Chemical Communications

Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(ii) frameworks†

Man-Sheng Chen,ab   Min Chen,a   Satoshi Takamizawa,c   Taka-aki Okamura,d   Jian Fana  and  Wei-Yin Sun*a  

* Corresponding authors

a Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China
E-mail: sunwy@nju.edu.cn
Fax: +86 25 8331 4502

b Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China

c Graduate School of Nanobioscience, Yokohama City University, Kanazawa-ku, Yokohama, Kanagawa 236-0027, Japan

d Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan

Abstract

A unique 4-fold interpenetrated (10,3)-b copper(II) framework exhibits reversible dehydration and rehydration in a single-crystal-to-single-crystal (SC–SC) process, and the dehydrated material can encapsulate CH3OH molecules, again in a SC–SC fashion, and shows selective adsorption of H2 and CO2 over N2.

Graphical abstract: Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(ii) frameworks

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Article information

DOI
https://doi.org/10.1039/C0CC04689B
Article type
Communication
Submitted
29 Oct 2010
Accepted
17 Jan 2011
First published
02 Feb 2011

Chem. Commun., 2011,47, 3787-3789

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Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frameworks

M. Chen, M. Chen, S. Takamizawa, T. Okamura, J. Fan and W. Sun, Chem. Commun., 2011, 47, 3787 DOI: 10.1039/C0CC04689B

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