Issue 12, 2011
From the journal:

Chemical Communications

Simple one-pot synthesis of Rh–Fe3O4 heterodimer nanocrystals and their applications to a magnetically recyclable catalyst for efficient and selective reduction of nitroarenes and alkenes†

Youngjin Jang,‡a   Seyoung Kim,‡b   Samuel Woojoo Jun,a   Byung Hyo Kim,a   Sunhwan Hwang,c   In Kyu Song,c   B. Moon Kim*b  and  Taeghwan Hyeon*a  

* Corresponding authors

a National Creative Research Initiative Center for Oxide Nanocrystalline Materials, World Class University Program of Chemical Convergence for Energy & Environment, and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-744, Korea
E-mail: thyeon@snu.ac.kr
Fax: +82 2-886-8457
Tel: +82 2-880-7150

b Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea
E-mail: kimbm@snu.ac.kr
Fax: +82 2-872-7505
Tel: +82-2-880-6644

c School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Seoul 151-744, Korea

Abstract

A simple synthesis of Rh–Fe3O4 heterodimer nanocrystals was achieved by controlled one-pot thermolysis. The nanocrystals exhibited excellent activities for the selective reduction of nitroarenes and alkenes. Furthermore the nanocrystal catalyst could be easily separated by a magnet, and recycled eight times without losing the catalytic activity.

Graphical abstract: Simple one-pot synthesis of Rh–Fe3O4 heterodimer nanocrystals and their applications to a magnetically recyclable catalyst for efficient and selective reduction of nitroarenes and alkenes

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Article information

DOI
https://doi.org/10.1039/C0CC04816J
Article type
Communication
Submitted
05 Nov 2010
Accepted
07 Jan 2011
First published
04 Feb 2011

Chem. Commun., 2011,47, 3601-3603

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Simple one-pot synthesis of Rh–Fe3O4 heterodimer nanocrystals and their applications to a magnetically recyclable catalyst for efficient and selective reduction of nitroarenes and alkenes

Y. Jang, S. Kim, S. W. Jun, B. H. Kim, S. Hwang, I. K. Song, B. M. Kim and T. Hyeon, Chem. Commun., 2011, 47, 3601 DOI: 10.1039/C0CC04816J

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