Issue 9, 2011
From the journal:

Chemical Communications

Formation of chiral mesostructured porphyrin–silica hybrids†

Huibin Qiu,‡a   Junjie Xie‡a  and  Shunai Che*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, P. R. China
E-mail: chesa@sjtu.edu.cn
Fax: +86 21-5474-5365

Abstract

Formation of a chiral mesostructured porphyrin–silica hybrid with cylindrical helical stacking of anionic porphyrins was achieved by the aid of cationic organosilane. The enantiopurity of the hybrid was dramatically enhanced by a small amount of (R)-1,1′-bi-2-naphthol or its enantiomer.

Graphical abstract: Formation of chiral mesostructured porphyrin–silica hybrids

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Article information

DOI
https://doi.org/10.1039/C0CC05078D
Article type
Communication
Submitted
21 Nov 2010
Accepted
14 Dec 2010
First published
13 Jan 2011

Chem. Commun., 2011,47, 2607-2609

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Formation of chiral mesostructured porphyrin–silica hybrids

H. Qiu, J. Xie and S. Che, Chem. Commun., 2011, 47, 2607 DOI: 10.1039/C0CC05078D

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