Issue 9, 2011
From the journal:

Chemical Communications

Me2–NHC based robust Ir catalyst for efficient water oxidation†

Dennis G. H. Hetterscheid*a  and  Joost N. H. Reeka  

* Corresponding authors

a Van ‘t Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands
E-mail: d.g.h.hetterscheid@uva.nl
Fax: +31 20 5255604
Tel: +31 20 5256459

Abstract

Me2–NHC proved to be a valuable ligand in iridium catalyzed water oxidation reactions, both when carried out electrochemically as well as upon oxidation with cerium ammonium nitrate. Mechanistic data suggest that water oxidation occurs efficiently at a well defined iridium species via a mononuclear pathway.

Graphical abstract: Me2–NHC based robust Ir catalyst for efficient water oxidation

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Article information

DOI
https://doi.org/10.1039/C0CC05108J
Article type
Communication
Submitted
22 Nov 2010
Accepted
18 Dec 2010
First published
11 Jan 2011

Chem. Commun., 2011,47, 2712-2714

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Me2–NHC based robust Ir catalyst for efficient water oxidation

D. G. H. Hetterscheid and J. N. H. Reek, Chem. Commun., 2011, 47, 2712 DOI: 10.1039/C0CC05108J

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