Steric control of conformation in self-assembly metallacalix[4]arenes derived from AlMe3 or GaMe3 with benzimidazolyl ligands

Ernesto Rufino-Felipe; Miguel-Ángel Muñoz-Hernández

doi:10.1039/C0CC05438K

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Steric control of conformation in self-assembly metallacalix[4]arenes derived from AlMe₃ or GaMe₃ with benzimidazolyl ligands†

Ernesto Rufino-Felipe^a and Miguel-Ángel Muñoz-Hernández*^a

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* Corresponding authors

^a Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, Col. Chamilpa, Cuernavaca, Morelos, Mexico
E-mail: mamund2@.uaem.mx
Fax: +52 777 3297997
Tel: +52 777 3297998

Abstract

Metallacalix[4]arenes [bzimAlMe₂]₄ (1), [bzimGaMe₂]₄ (2), [mbzimAlMe₂]₄ (3) and [mbzimGaMe₂]₄ (4) were obtained by self-assembly. The larger cavity of 3 and 4 allows them to function as hosts of benzene molecules.

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Article information

DOI: https://doi.org/10.1039/C0CC05438K
Article type: Communication
Submitted: 07 Dec 2010
Accepted: 13 Jan 2011
First published: 01 Feb 2011

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Chem. Commun., 2011,47, 3210-3212

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Steric control of conformation in self-assembly metallacalix[4]arenes derived from AlMe₃ or GaMe₃ with benzimidazolyl ligands

E. Rufino-Felipe and M. Muñoz-Hernández, Chem. Commun., 2011, 47, 3210 DOI: 10.1039/C0CC05438K

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