A high nuclearity mixed valence {Mn32} complex

Stuart K. Langley; Rachel A. Stott; Nicholas F. Chilton; Boujemaa Moubaraki; Keith S. Murray

doi:10.1039/C1CC00035G

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A high nuclearity mixed valence {Mn₃₂} complex†

Stuart K. Langley,^a Rachel A. Stott,^a Nicholas F. Chilton,^a Boujemaa Moubaraki^a and Keith S. Murray*^a

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* Corresponding authors

^a School of Chemistry, Monash University, Clayton, Victoria 3800, Australia
E-mail: Keith.murray@monash.edu

Abstract

A mixed-valence {Mn₃₂} complex, containing Mn^II, Mn^III and Mn^IV ions, with a probable S = 5 ground state, utilizes pivalate as a capping ligand and a variety of oxo-type bridging ligands. AC susceptibility data on fresh samples suggest that the Mn₃₂ complex is one of the largest nuclearity single molecule magnets found to date.

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Article information

DOI: https://doi.org/10.1039/C1CC00035G
Article type: Communication
Submitted: 04 Jan 2011
Accepted: 05 Apr 2011
First published: 19 Apr 2011

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Chem. Commun., 2011,47, 6281-6283

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A high nuclearity mixed valence {Mn₃₂} complex

S. K. Langley, R. A. Stott, N. F. Chilton, B. Moubaraki and K. S. Murray, Chem. Commun., 2011, 47, 6281 DOI: 10.1039/C1CC00035G

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