Issue 22, 2011
From the journal:

Chemical Communications

Plastic crystalline lithium salt with solid-state ionic conductivity and high lithium transport number†

Makoto Moriya,ab   Daiki Kato,a   Wataru Sakamotoa  and  Toshinobu Yogo*a  

* Corresponding authors

a Division of Nanomaterial Science, EcoTopia Science Institute, Nagoya University, 464-8603, Furo-cho, Chikusa-ku, Nagoya, Japan
E-mail: yogo@esi.nagoya-u.ac.jp
Fax: +81 52 789 2121
Tel: +81 52 789 2750

b PRESTO, Japan Science and Technology Agency (JST), 4-1-8 Honcho Kawaguchi, Saitama 332-0012, Japan

Abstract

Plastic crystallinity of lithium salt, [LiB(OCH2CH2OCH3)4] (1), and its solid-state ionic conductivity are disclosed. The addition of small amounts of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) to borate 1 led to the drastic increase of the ionic conductivity and lithium transport number of the electrolyte.

Graphical abstract: Plastic crystalline lithium salt with solid-state ionic conductivity and high lithium transport number

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Article information

DOI
https://doi.org/10.1039/C1CC00070E
Article type
Communication
Submitted
05 Jan 2011
Accepted
07 Apr 2011
First published
21 Apr 2011

Chem. Commun., 2011,47, 6311-6313

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Plastic crystalline lithium salt with solid-state ionic conductivity and high lithium transport number

M. Moriya, D. Kato, W. Sakamoto and T. Yogo, Chem. Commun., 2011, 47, 6311 DOI: 10.1039/C1CC00070E

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