Issue 15, 2011
From the journal:

Chemical Communications

Ionic liquid catalysed reaction of thiols with α,β-unsaturated carbonyl compounds—remarkable influence of the C-2 hydrogen and the anion†

Anirban Sarkar,a   Sudipta Raha Roya  and  Asit K. Chakraborti*a  

* Corresponding authors

a Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER), Sector 67, S. A. S. Nagar, Punjab 160 062, India
E-mail: akchakraborti@niper.ac.in
Fax: +91 (0)172 2214692
Tel: +91 (0)172 2214683

Abstract

Hydrogen bond induced reactivity and selectivity control in the 1-butyl-3-methylimidazolium based ionic liquid catalysed reaction of thiols with α,β-unsaturated carbonyl compounds is reported with remarkable influence of the anion and the C-2 hydrogen in catalytic activity and reversal of selectivity.

Graphical abstract: Ionic liquid catalysed reaction of thiols with α,β-unsaturated carbonyl compounds—remarkable influence of the C-2 hydrogen and the anion

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Article information

DOI
https://doi.org/10.1039/C1CC10151J
Article type
Communication
Submitted
08 Jan 2011
Accepted
21 Feb 2011
First published
09 Mar 2011

Chem. Commun., 2011,47, 4538-4540

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Ionic liquid catalysed reaction of thiols with α,β-unsaturated carbonyl compounds—remarkable influence of the C-2 hydrogen and the anion

A. Sarkar, S. R. Roy and A. K. Chakraborti, Chem. Commun., 2011, 47, 4538 DOI: 10.1039/C1CC10151J

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