Issue 12, 2011
From the journal:

Chemical Communications

New insights into the mechanism of activation of atom transfer radical polymerization by Cu(i) complexes†

Patrizia De Paoli,a   Abdirisak A. Isse,*a   Nicola Bortolameia  and  Armando Gennaroa  

* Corresponding authors

a Department of Chemical Sciences, University of Padova, via Marzolo 1, Padova, Italy
E-mail: abdirisak.ahmedisse@unipd.it
Fax: +39 049 8275239
Tel: +39 049 8275677

Abstract

The kinetics of activation of RX by a CuI complex has been investigated in MeCN both in the absence and presence of halide ions. The system CuI/L/X− (L = Me6TREN) is mainly composed of CuIL+, XCuIL and CuIX2−, but only CuIL+ is found to be an active catalyst reacting with RX.

Graphical abstract: New insights into the mechanism of activation of atom transfer radical polymerization by Cu(i) complexes

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Article information

DOI
https://doi.org/10.1039/C1CC10195A
Article type
Communication
Submitted
11 Jan 2011
Accepted
31 Jan 2011
First published
16 Feb 2011

Chem. Commun., 2011,47, 3580-3582

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New insights into the mechanism of activation of atom transfer radical polymerization by Cu(I) complexes

P. De Paoli, A. A. Isse, N. Bortolamei and A. Gennaro, Chem. Commun., 2011, 47, 3580 DOI: 10.1039/C1CC10195A

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