Issue 13, 2011

New polycyclic borazine species

Abstract

The new polycyclic borazines B2{1,2-N2C6H4}2{B2(NMe2)2}2, B2{1,8-N2naph}2{B2(NMe2)2}2 and B2(NPh)4{B2(NMe2)2}2 have been prepared from diborate(4) anions and two equivalents of B2Cl2(NMe2)2 and have been structurally characterised. Aspects of their structure and bonding are discussed and comparison made with corresponding polycyclic aromatic hydrocarbons.

Graphical abstract: New polycyclic borazine species

Supplementary files

Article information

Article type
Communication
Submitted
11 Jan 2011
Accepted
10 Feb 2011
First published
24 Feb 2011

Chem. Commun., 2011,47, 3748-3750

New polycyclic borazine species

X. Xie, M. F. Haddow, S. M. Mansell, N. C. Norman and C. A. Russell, Chem. Commun., 2011, 47, 3748 DOI: 10.1039/C1CC10196J

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