Issue 25, 2011

Arylation of α-pivaloxyl ketones with arylboronic reagents viaNi-catalyzed sp3 C–O activation

Abstract

A Suzuki–Miyaura coupling of α-pivaloxyl ketonesviaNi-catalyzed sp3 C–O activation to produce α-aryl ketones is developed. This study offers a convenient method to construct α-arylation products from readily available α-hydroxyl carbonyl compounds.

Graphical abstract: Arylation of α-pivaloxyl ketones with arylboronic reagents viaNi-catalyzed sp3 C–O activation

Supplementary files

Article information

Article type
Communication
Submitted
28 Feb 2011
Accepted
28 Apr 2011
First published
27 May 2011

Chem. Commun., 2011,47, 7224-7226

Arylation of α-pivaloxyl ketones with arylboronic reagents viaNi-catalyzed sp3 C–O activation

K. Huang, G. Li, W. Huang, D. Yu and Z. Shi, Chem. Commun., 2011, 47, 7224 DOI: 10.1039/C1CC11193K

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