Issue 21, 2011
From the journal:

Chemical Communications

Sodium and barium cation-templated synthesis and cation-induced molecular pirouetting of a pyridine N-oxide containing [2]rotaxane†‡

Laura M. Hancocka  and  Paul D. Beer*a  

* Corresponding authors

a Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, UK
E-mail: paul.beer@chem.ox.ac.uk
Fax: +44 (0)1865 272960
Tel: +44 (0)1865 285182

Abstract

Sodium and barium metal cation templation has been used to construct a novel pyridine N-oxide containing [2]rotaxane. Upon addition and removal of metal cations, the macrocyclic component is observed to undergo a pirouetting motion around the pyridine N-oxide axle.

Graphical abstract: Sodium and barium cation-templated synthesis and cation-induced molecular pirouetting of a pyridine N-oxide containing [2]rotaxane

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Article information

DOI
https://doi.org/10.1039/C1CC11224D
Article type
Communication
Submitted
01 Mar 2011
Accepted
22 Mar 2011
First published
11 Apr 2011

Chem. Commun., 2011,47, 6012-6014

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Sodium and barium cation-templated synthesis and cation-induced molecular pirouetting of a pyridine N-oxide containing [2]rotaxane

L. M. Hancock and P. D. Beer, Chem. Commun., 2011, 47, 6012 DOI: 10.1039/C1CC11224D

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