Issue 23, 2011
From the journal:

Chemical Communications

Preferential carbene insertion into Ge–H vs. other heavier group 14 hydridesviasamarium carbenoids†

Hitoshi Kondo,a   Yoshinori Yamanoi*a  and  Hiroshi Nishihara*a  

* Corresponding authors

a Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: yamanoi@chem.s.u-tokyo.ac.jp, nisihara@chem.s.u-tokyo.ac.jp
Fax: +81-3-5841-8063
Tel: +81-3-5841-4346

Abstract

The relative reactivities of Zn, Al, and Sm carbenoids in the chemoselective carbene insertion reaction of heavier group 14 hydrides were studied. By variation of the reaction protocols using Sm carbenoids, insertion reaction can favour the Ge–H bonds to give Ge-alkylated derivatives in good to high yield.

Graphical abstract: Preferential carbene insertion into Ge–H vs. other heavier group 14 hydridesviasamarium carbenoids

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Article information

DOI
https://doi.org/10.1039/C1CC11256B
Article type
Communication
Submitted
03 Mar 2011
Accepted
21 Apr 2011
First published
10 May 2011

Chem. Commun., 2011,47, 6671-6673

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Preferential carbene insertion into Ge–H vs. other heavier group 14 hydridesviasamarium carbenoids

H. Kondo, Y. Yamanoi and H. Nishihara, Chem. Commun., 2011, 47, 6671 DOI: 10.1039/C1CC11256B

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