Issue 22, 2011
From the journal:

Chemical Communications

Organic–inorganic hybrid materials starting from the novel nanoscaled bismuth oxido methacrylate cluster [Bi38O45(OMc)24(DMSO)9]·2DMSO·7H2O†

Linda Miersch,a   Tobias Rüffera  and  Michael Mehring*a  

* Corresponding authors

a Professur für Koordinationschemie, Technische Universität Chemnitz, Straße der Nationen 62, Chemnitz, Germany
E-mail: michael.mehring@chemie.tu-chemnitz.de
Fax: +49 371-53121219

Abstract

The reaction of the basic bismuth nitrate [Bi6O4(OH)4](NO3)6·H2O with sodium methacrylate in DMSO gave [Bi38O45(OMc)24(DMSO)9]·2DMSO·7H2O (OMc = O2CC3H5), which is highly soluble in organic solvents. By copolymerization of the bismuth oxido cluster with methyl methacrylate transparent, radiopaque organic–inorganic hybrid materials were obtained.

Graphical abstract: Organic–inorganic hybrid materials starting from the novel nanoscaled bismuth oxido methacrylate cluster [Bi38O45(OMc)24(DMSO)9]·2DMSO·7H2O

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Article information

DOI
https://doi.org/10.1039/C1CC11299F
Article type
Communication
Submitted
04 Mar 2011
Accepted
11 Apr 2011
First published
03 May 2011

Chem. Commun., 2011,47, 6353-6355

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Organic–inorganic hybrid materials starting from the novel nanoscaled bismuth oxido methacrylate cluster [Bi38O45(OMc)24(DMSO)9]·2DMSO·7H2O

L. Miersch, T. Rüffer and M. Mehring, Chem. Commun., 2011, 47, 6353 DOI: 10.1039/C1CC11299F

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