Issue 20, 2011
From the journal:

Chemical Communications

The hafnium-mediated NH activation of an amido-borane†

Elizabeth A. Jacobs,a   Anna-Marie Fuller,a   Simon J. Lancaster*a  and  Joseph A. Wrighta  

* Corresponding authors

a Energy Materials Laboratory, School of Chemistry, University of East Anglia, Norwich, UK
E-mail: S.Lancaster@uea.ac.uk
Fax: +44 (0)1603 592003
Tel: +44 (0)1603 592009

Abstract

Treatment of Cp2HfCl2 with two equivalents of LiNH2BH(C6F5)2 in toluene solution yields Cp2Hf{NHBH(C6F5)2}, which has been crystallographically characterised. The otherwise base-free [NHBH(C6F5)2] complex is stabilised by an agostic interaction.

Graphical abstract: The hafnium-mediated NH activation of an amido-borane

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Article information

DOI
https://doi.org/10.1039/C1CC11320H
Article type
Communication
Submitted
07 Mar 2011
Accepted
05 Apr 2011
First published
18 Apr 2011

Chem. Commun., 2011,47, 5870-5872

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The hafnium-mediated NH activation of an amido-borane

E. A. Jacobs, A. Fuller, S. J. Lancaster and J. A. Wright, Chem. Commun., 2011, 47, 5870 DOI: 10.1039/C1CC11320H

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