Issue 20, 2011
From the journal:

Chemical Communications

Direct functionalisation of group 10 N-heterocyclic carbene complexes for diversity enhancement†

Edith Chardon,ab   Gian Luigi Puleo,a   Georges Dahm,a   Gilles Guichard*b  and  Stéphane Bellemin-Laponnaz*a  

* Corresponding authors

a Institute of Physics and Chemistry of Materials of Strasbourg (IPCMS), University of Strasbourg – CNRS UMR7504, 23 rue du Loess, 67034 Strasbourg, France
E-mail: bellemin@unistra.fr
Fax: +33 (0)388107246
Tel: +33 (0)388107166

b European Institute of Chemistry and Biology (IECB), University of Bordeaux – CNRS UMR5248, 2 rue Escarpit, 33607 Pessac, France
E-mail: g.guichard@iecb.u-bordeaux.fr
Fax: +33 (0)540002200
Tel: +33 (0)540003020

Abstract

The synthesis of alkyne-substituted N-heterocyclic carbene complexes of Pd(II) and Pt(II) is reported. Catalyzed 1,3-dipolar cycloaddition with azides has been applied as a modular way of functionalisation of group 10 transition metal NHC complexes to generate potentially new metallodrugs.

Graphical abstract: Direct functionalisation of group 10 N-heterocyclic carbene complexes for diversity enhancement

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Article information

DOI
https://doi.org/10.1039/C1CC11391G
Article type
Communication
Submitted
10 Mar 2011
Accepted
01 Apr 2011
First published
18 Apr 2011

Chem. Commun., 2011,47, 5864-5866

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Direct functionalisation of group 10 N-heterocyclic carbene complexes for diversity enhancement

E. Chardon, G. L. Puleo, G. Dahm, G. Guichard and S. Bellemin-Laponnaz, Chem. Commun., 2011, 47, 5864 DOI: 10.1039/C1CC11391G

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