Issue 25, 2011
From the journal:

Chemical Communications

4-Nitrophenyl sulfenyl chloride as a new precursor for the formation of aromatic SAMs on gold surfaces†

Abdelaziz Houmam,*a   Hamida Muhammad,a   M'hamed Chahma,a   Kallum Koczkura  and  Daniel F. Thomasa  

* Corresponding authors

a Electrochemical Technology Centre, Department of Chemistry, University of Guelph, Guelph, Ontario, Canada
E-mail: ahoumam@uoguelph.ca
Fax: +519 7661499
Tel: +519 8244120

Abstract

4-Nitrophenyl sulfenyl chloride was used as a new precursor for the formation of densely packed aromatic SAMs on gold. The adsorption involves the reductive dissociation of the S–Cl bond. A well-ordered row structure corresponding to a √3 × 4 phase with a molecular area of 27.8 Å2 is obtained.

Graphical abstract: 4-Nitrophenyl sulfenyl chloride as a new precursor for the formation of aromatic SAMs on gold surfaces

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Article information

DOI
https://doi.org/10.1039/C1CC11451D
Article type
Communication
Submitted
14 Mar 2011
Accepted
07 May 2011
First published
27 May 2011

Chem. Commun., 2011,47, 7095-7097

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4-Nitrophenyl sulfenyl chloride as a new precursor for the formation of aromatic SAMs on gold surfaces

A. Houmam, H. Muhammad, M. Chahma, K. Koczkur and D. F. Thomas, Chem. Commun., 2011, 47, 7095 DOI: 10.1039/C1CC11451D

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