Issue 20, 2011
From the journal:

Chemical Communications

Surfactant-free synthesis of palladium nanoclusters for their use in catalytic cross-coupling reactions†

Megumi Hyotanishi,a   Yuto Isomura,a   Hiroko Yamamoto,a   Hideya Kawasakia  and  Yasushi Obora*a  

* Corresponding authors

a Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan
E-mail: obora@kansai-u.ac.jp
Fax: +81-6-6339-4026
Tel: +81-6-6368-0876

Abstract

Surfactant-free Pd nanoclusters (Pd NCs) (size: 1–1.5 nm) showed high catalytic activity in the Suzuki–Miyaura cross-coupling and Mizoroki–Heck reactions. The Pd NCs had a high turnover number, up to 6.0 × 108, which can be recycled at least five times without loss of catalytic activity.

Graphical abstract: Surfactant-free synthesis of palladium nanoclusters for their use in catalytic cross-coupling reactions

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Article information

DOI
https://doi.org/10.1039/C1CC11487E
Article type
Communication
Submitted
15 Mar 2011
Accepted
05 Apr 2011
First published
18 Apr 2011

Chem. Commun., 2011,47, 5750-5752

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Surfactant-free synthesis of palladium nanoclusters for their use in catalytic cross-coupling reactions

M. Hyotanishi, Y. Isomura, H. Yamamoto, H. Kawasaki and Y. Obora, Chem. Commun., 2011, 47, 5750 DOI: 10.1039/C1CC11487E

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