Issue 23, 2011

Octaalkyl tetracene-1,2,3,4,7,8,9,10-octacarboxylates: synthesis by twofold [2+2+2] cocyclization and crystallochromy

Abstract

Tetracene octaesters, which were prepared by twofold [2+2+2] cocyclization, were isolated as red, orange, and orange-yellow solids for the methyl, ethyl, and propyl ester derivatives, respectively. X-Ray crystallographic analysis reveals that the difference in solid-state color arises owing to differences in molecular packing.

Graphical abstract: Octaalkyl tetracene-1,2,3,4,7,8,9,10-octacarboxylates: synthesis by twofold [2+2+2] cocyclization and crystallochromy

Supplementary files

Article information

Article type
Communication
Submitted
22 Mar 2011
Accepted
12 Apr 2011
First published
03 May 2011

Chem. Commun., 2011,47, 6653-6655

Octaalkyl tetracene-1,2,3,4,7,8,9,10-octacarboxylates: synthesis by twofold [2+2+2] cocyclization and crystallochromy

C. Kitamura, A. Takenaka, T. Kawase, T. Kobayashi and H. Naito, Chem. Commun., 2011, 47, 6653 DOI: 10.1039/C1CC11655J

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