Issue 24, 2011
From the journal:

Chemical Communications

First enantioselective iron-porphyrin-catalyzed sulfideoxidation with aqueous hydrogen peroxide†‡

Paul Le Mauxa  and  Gérard Simonneaux*a  

* Corresponding authors

a Ingénierie Chimique et Molécules pour le Vivant, UMR CNRS 6226, Campus de Beaulieu, Université de Rennes 1, 35042 Rennes, France
E-mail: gerard.simonneaux@univ-rennes1.fr
Fax: +33 (0)223235637
Tel: +33 (0)223236285

Abstract

The asymmetric oxidation of sulfides by H2O2 to give optically active sulfoxides (ee up to 90%) was carried out in methanol and water using chiral water-soluble iron porphyrins as catalysts.

Graphical abstract: First enantioselective iron-porphyrin-catalyzed sulfide oxidation with aqueous hydrogen peroxide

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Article information

DOI
https://doi.org/10.1039/C1CC11675D
Article type
Communication
Submitted
23 Mar 2011
Accepted
21 Apr 2011
First published
10 May 2011

Chem. Commun., 2011,47, 6957-6959

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First enantioselective iron-porphyrin-catalyzed sulfide oxidation with aqueous hydrogen peroxide

P. Le Maux and G. Simonneaux, Chem. Commun., 2011, 47, 6957 DOI: 10.1039/C1CC11675D

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