Photocatalytic function of a polymer-supported B12 complex with a ruthenium trisbipyridine photosensitizer

Hisashi Shimakoshi; Masashi Nishi; Akihiro Tanaka; Katsumi Chikama; Yoshio Hisaeda

doi:10.1039/C1CC11970B

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Photocatalytic function of a polymer-supported B₁₂ complex with a ruthenium trisbipyridine photosensitizer†

Hisashi Shimakoshi,^a Masashi Nishi,^a Akihiro Tanaka,^ab Katsumi Chikama^b and Yoshio Hisaeda*^a

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* Corresponding authors

^a Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Motooka, Fukuoka 819-0395, Japan
E-mail: yhisatcm@mail.cstm.kyushu-u.ac.jp
Fax: +81-92-802-2827

^b Synthesis Research Dept., Chemical Research Lab., Nissan Chemical Industries, Ltd., Funabashi 274-8507, Japan

Abstract

The hybrid polymer was synthesized by a radical polymerization of a B₁₂ derivative and a Ru complex having styrene moieties in each peripheral position, and the hybrid polymer showed photocatalytic activity for molecular transformation with visible light irradiation.

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Article information

DOI: https://doi.org/10.1039/C1CC11970B
Article type: Communication
Submitted: 07 Apr 2011
Accepted: 19 Apr 2011
First published: 09 May 2011

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Chem. Commun., 2011,47, 6548-6550

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Photocatalytic function of a polymer-supported B₁₂ complex with a ruthenium trisbipyridine photosensitizer

H. Shimakoshi, M. Nishi, A. Tanaka, K. Chikama and Y. Hisaeda, Chem. Commun., 2011, 47, 6548 DOI: 10.1039/C1CC11970B

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Chemical Communications