Issue 29, 2011
From the journal:

Chemical Communications

Comparison of molecular conductance between planar and twisted 4-phenylpyridines by means of two-dimensional phase separation of tetraphenylporphyrin templates at a liquid–HOPG interface†

Takeshi Sakano,a   Kenji Higashiguchia  and  Kenji Matsuda*a  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: kmatsuda@sbchem.kyoto-u.ac.jp

Abstract

Tetraphenylporphyrin (TPP) rhodium chlorides coordinated by planar and twisted 4-phenylpyridine derivatives were synthesized. An STM image was taken by a 2-D phase separation technique and the conductance was evaluated. Difference in apparent height between these phenylpyridines reflects the conductance ratio of ligands.

Graphical abstract: Comparison of molecular conductance between planar and twisted 4-phenylpyridines by means of two-dimensional phase separation of tetraphenylporphyrin templates at a liquid–HOPG interface

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Article information

DOI
https://doi.org/10.1039/C1CC12041G
Article type
Communication
Submitted
11 Apr 2011
Accepted
08 Jun 2011
First published
24 Jun 2011

Chem. Commun., 2011,47, 8427-8429

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Comparison of molecular conductance between planar and twisted 4-phenylpyridines by means of two-dimensional phase separation of tetraphenylporphyrin templates at a liquid–HOPG interface

T. Sakano, K. Higashiguchi and K. Matsuda, Chem. Commun., 2011, 47, 8427 DOI: 10.1039/C1CC12041G

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