Issue 33, 2011
From the journal:

Chemical Communications

A photo-induced excited state structure of a hetero-bimetallic ionic pair complex, Nd(DMA)4(H2O)4Fe(CN)6·3H2O, analyzed by single crystal X-ray diffraction†

Helle Svendsen,a   Jacob Overgaard,a   Yu-Sheng Chenb  and  Bo B. Iversen*a  

* Corresponding authors

a Centre for Materials Crystallography, Department of Chemistry and iNANO, Aarhus University, DK-8000 Aarhus C, Denmark
E-mail: bo@chem.au.dk
Fax: +45 8619 6199

b ChemMatCARS beam line, The University of Chicago, Advanced Photon Source, Argonne, USA

Abstract

The excited state crystal structure of the ionic complex (Nd(DMA)4(H2O)4–Fe(CN)6·3H2O (DMA = dimethylacetamide) has been determined at 15 K upon UV illumination by single crystal X-ray diffraction. Significant structural changes are observed around the Fe site in the excited state. These changes are similar to those observed for a related molecular compound exhibiting photomagnetic properties.

Graphical abstract: A photo-induced excited state structure of a hetero-bimetallic ionic pair complex, Nd(DMA)4(H2O)4Fe(CN)6·3H2O, analyzed by single crystal X-ray diffraction

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Article information

DOI
https://doi.org/10.1039/C1CC12626A
Article type
Communication
Submitted
04 May 2011
Accepted
11 Jul 2011
First published
25 Jul 2011

Chem. Commun., 2011,47, 9486-9488

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A photo-induced excited state structure of a hetero-bimetallic ionic pair complex, Nd(DMA)4(H2O)4Fe(CN)6·3H2O, analyzed by single crystal X-ray diffraction

H. Svendsen, J. Overgaard, Y. Chen and B. B. Iversen, Chem. Commun., 2011, 47, 9486 DOI: 10.1039/C1CC12626A

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