Issue 29, 2011

Ir-catalysed formation of C−F bonds. From allylic alcohols to α-fluoroketones

Abstract

A novel iridium-catalysed tandem isomerisation/C–F bond formation from allylic alcohols and Selectfluor® to prepare α-fluorinated ketones as single constitutional isomers is reported.

Graphical abstract: Ir-catalysed formation of C−F bonds. From allylic alcohols to α-fluoroketones

Supplementary files

Article information

Article type
Communication
Submitted
05 May 2011
Accepted
31 May 2011
First published
22 Jun 2011
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2011,47, 8331-8333

Ir-catalysed formation of C−F bonds. From allylic alcohols to α-fluoroketones

N. Ahlsten and B. Martín-Matute, Chem. Commun., 2011, 47, 8331 DOI: 10.1039/C1CC12653A

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