Issue 30, 2011
From the journal:

Chemical Communications

From attraction to repulsion: anion–π interactions between bromide and fluorinated phenyl groups†‡

Michael Giese,a   Markus Albrecht,*a   Christoph Bannwarth,a   Gerhard Raabe,a   Arto Valkonenb  and  Kari Rissanen*b  

* Corresponding authors

a Institut für Organische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
E-mail: markus.albrecht@oc.rwth-aachen.de

b Department of Chemistry, Nanoscience Center, University of Jyväskylä, Survontie 9, P.O. Box 35, Finland
E-mail: kari.t.rissanen@jyu.fi

Abstract

Anion–π interactions in crystals of fluorobenzyl ammonium salts depend on the degree of fluorination at the aromatics.

Graphical abstract: From attraction to repulsion: anion–π interactions between bromide and fluorinated phenyl groups

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Article information

DOI
https://doi.org/10.1039/C1CC12667A
Article type
Communication
Submitted
06 May 2011
Accepted
07 Jun 2011
First published
27 Jun 2011

Chem. Commun., 2011,47, 8542-8544

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From attraction to repulsion: anion–π interactions between bromide and fluorinated phenyl groups

M. Giese, M. Albrecht, C. Bannwarth, G. Raabe, A. Valkonen and K. Rissanen, Chem. Commun., 2011, 47, 8542 DOI: 10.1039/C1CC12667A

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