Issue 28, 2011

New environmentally friendly catalysts containing Pd–interstitial carbon made from Pd–glucose precursors for ultraselective hydrogenations in the liquid phase

Abstract

We report a novel preparation of a Pd nanocatalyst modified with subsurface C via blending a glucose precursor at the molecular level: the catalyst is demonstrated for the first time to be stereoselective in the hydrogenation of alkynes to cis-alkenes in the liquid phase.

Graphical abstract: New environmentally friendly catalysts containing Pd–interstitial carbon made from Pd–glucose precursors for ultraselective hydrogenations in the liquid phase

Supplementary files

Article information

Article type
Communication
Submitted
06 May 2011
Accepted
02 Jun 2011
First published
16 Jun 2011

Chem. Commun., 2011,47, 7971-7973

New environmentally friendly catalysts containing Pd–interstitial carbon made from Pd–glucose precursors for ultraselective hydrogenations in the liquid phase

C. W. A. Chan, Y. Xie, N. Cailuo, K. M. K. Yu, J. Cookson, P. Bishop and S. C. Tsang, Chem. Commun., 2011, 47, 7971 DOI: 10.1039/C1CC12681D

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