The rational synthesis of (10,3)-type MOFs based on tetranuclear [W(Mo)OS3Cu3]+ secondary building units

Xiao-Qiang Yao; Zhao-Rui Pan; Jin-Song Hu; Yi-Zhi Li; Zi-Jian Guo; He-Gen Zheng

doi:10.1039/C1CC12691A

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The rational synthesis of (10,3)-type MOFs based on tetranuclear [W(Mo)OS₃Cu₃]⁺ secondary building units†

Xiao-Qiang Yao,^a Zhao-Rui Pan,^a Jin-Song Hu,^a Yi-Zhi Li,^a Zi-Jian Guo^a and He-Gen Zheng*^ab

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* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P.R. China
E-mail: zhenghg@nju.edu.cn
Fax: +86-25-83314502

^b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China

Abstract

The self-assembly reaction of the preformed clusters with two extended linear and trigonal rigid ligands as organic linkers afforded two 2D and 3D Mo(W)/Cu/S-based cluster polymers. They show unprecedented structure types in Mo(W)/S/Cu chemistry and exhibit strong third-order nonlinear optical properties.

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Article information

DOI: https://doi.org/10.1039/C1CC12691A
Article type: Communication
Submitted: 07 May 2011
Accepted: 20 Jul 2011
First published: 08 Aug 2011

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Chem. Commun., 2011,47, 10049-10051

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The rational synthesis of (10,3)-type MOFs based on tetranuclear [W(Mo)OS₃Cu₃]⁺ secondary building units

X. Yao, Z. Pan, J. Hu, Y. Li, Z. Guo and H. Zheng, Chem. Commun., 2011, 47, 10049 DOI: 10.1039/C1CC12691A

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