Issue 30, 2011

Aryne reaction with trifluoromethylketones in three modes: C–C bond cleavage, [2+2] cycloaddition and O-arylation

Abstract

Trifluoromethyl ketones were found to be coupled with arynes in three modes depending upon their substitution patterns, namely C–C bond cleavage, [2+2] cycloaddition and O-arylation.

Graphical abstract: Aryne reaction with trifluoromethyl ketones in three modes: C–C bond cleavage, [2+2] cycloaddition and O-arylation

Supplementary files

Article information

Article type
Communication
Submitted
13 May 2011
Accepted
17 Jun 2011
First published
27 Jun 2011

Chem. Commun., 2011,47, 8664-8666

Aryne reaction with trifluoromethyl ketones in three modes: C–C bond cleavage, [2+2] cycloaddition and O-arylation

H. Yoshida, Y. Ito, Y. Yoshikawa, J. Ohshita and K. Takaki, Chem. Commun., 2011, 47, 8664 DOI: 10.1039/C1CC12820E

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