Issue 31, 2011
From the journal:

Chemical Communications

Introducing an amine functionality at the block junction of amphiphilic block copolymers by anionic polymerization strategies†

Christoph Tonhauser,a   Boris Obermeier,a   Christine Mangold,a   Holger Löweab  and  Holger Frey*a  

* Corresponding authors

a Institute of Organic Chemistry, Johannes Gutenberg-University Mainz, Duesbergweg 10-14, 55099 Mainz, Germany
E-mail: hfrey@uni-mainz.de
Fax: +49 6131 3926106
Tel: +49 6131 3924078

b Institut für Mikrotechnik Mainz GmbH, Carl-Zeiss-Strasse 18-22, 55129 Mainz, Germany

Abstract

A series of block copolymers bearing a single amino in-chain functionality was synthesized viaanionic polymerization of styrene and ethylene oxide. By means of both a conventional and a continuous setup, living polystyrene was quantitatively end functionalized with an oxirane (DBAG) prior to the polymerization of the poly(ethylene oxide) segment. The in-chain amine was conjugated with a fluorescent dye.

Graphical abstract: Introducing an amine functionality at the block junction of amphiphilic block copolymers by anionic polymerization strategies

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Article information

DOI
https://doi.org/10.1039/C1CC12956B
Article type
Communication
Submitted
19 May 2011
Accepted
23 Jun 2011
First published
07 Jul 2011

Chem. Commun., 2011,47, 8964-8966

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Introducing an amine functionality at the block junction of amphiphilic block copolymers by anionic polymerization strategies

C. Tonhauser, B. Obermeier, C. Mangold, H. Löwe and H. Frey, Chem. Commun., 2011, 47, 8964 DOI: 10.1039/C1CC12956B

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