Issue 36, 2011
From the journal:

Chemical Communications

Metal-free aerobic oxidative coupling of amines to imines†

Lianghui Liu,a   Siyu Zhang,a   Xuefeng Fu*a  and  Chun-Hua Yana  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: fuxf@pku.edu.cn
Fax: +86 10-6275-1708
Tel: +86 10-6275-6035

Abstract

Oxidative coupling of primary amines to imines is achieved with high to moderate yields by refluxing suspensions of amines and water under one atmosphere dioxygen without any additives. Tandem acid-free aza Diels–Alder reactions for synthesis of N-alkyl-4-pyridones are also accomplished.

Graphical abstract: Metal-free aerobic oxidative coupling of amines to imines

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Article information

DOI
https://doi.org/10.1039/C1CC13202D
Article type
Communication
Submitted
31 May 2011
Accepted
27 Jul 2011
First published
10 Aug 2011

Chem. Commun., 2011,47, 10148-10150

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Metal-free aerobic oxidative coupling of amines to imines

L. Liu, S. Zhang, X. Fu and C. Yan, Chem. Commun., 2011, 47, 10148 DOI: 10.1039/C1CC13202D

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