Issue 40, 2011
From the journal:

Chemical Communications

Relationship between crystal packing and high electron mobility in the single crystal of thienyl-substituted methanofullerene†

Jung Hei Choi,a   Tatsuhiko Honda,a   Shu Seki*b  and  Shunichi Fukuzumi*ac  

* Corresponding authors

a Department of Material and Life Science, Graduate School of Engineering, Osaka University, Yamada-oka, ALCA, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871, Japan
E-mail: fukuzumi@chem.eng.osaka-u.ac.jp
Fax: +81 6-6879-7370
Tel: +81 6-6879-7369

b Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan
E-mail: seki@chem.eng.osaka-u.ac.jp
Fax: +81 6-6879-4588
Tel: +81 6-6879-4587

c Department of Bioinspired Science, Ewha Womans University, Seoul 120-750, Korea

Abstract

The X-ray crystal structure of 1-(3-methoxy-carbonyl)-propyl-1-thienyl-[6,6]-methanofullerene (ThCBM) was determined and the electron mobility of the single crystal was measured using a TRMC method to reveal high electron mobility (2 cm2 V−1 s−1) along the long axis (a-axis) and its remarkable anisotropy (7 times).

Graphical abstract: Relationship between crystal packing and high electron mobility in the single crystal of thienyl-substituted methanofullerene

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Article information

DOI
https://doi.org/10.1039/C1CC13228H
Article type
Communication
Submitted
01 Jun 2011
Accepted
01 Sep 2011
First published
19 Sep 2011

Chem. Commun., 2011,47, 11213-11215

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Relationship between crystal packing and high electron mobility in the single crystal of thienyl-substituted methanofullerene

J. H. Choi, T. Honda, S. Seki and S. Fukuzumi, Chem. Commun., 2011, 47, 11213 DOI: 10.1039/C1CC13228H

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