Redox tunable reversible molecular sieves: orthorhombic molybdenum vanadium oxide†
Abstract
We demonstrated that the sorption behavior of orthorhombic Mo–V oxide (Mo29V11O112−x) is continually and reversibly tunable by redox treatment.
* Corresponding authors
a
Chemistry and Chemical Engineering, Graduate School of Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima, Japan
E-mail:
sadakane09@hiroshima-u.ac.jp
Fax: (+81)82-424-5494
Tel: (+81)82-424-4456
b
Catalysis Research Center, Hokkaido University, N-21, W-10, Sapporo, Japan
E-mail:
ueda@cat.hokudai.ac.jp
Fax: (+81)11-706-9163
Tel: (+81)11-706-9164
c Research & Utilization Division, Japan Synchrotron Radiation Research Institute (JASRI), SPring-8, 1-1-1 Kouto, Sayo, Hyogo, Japan
We demonstrated that the sorption behavior of orthorhombic Mo–V oxide (Mo29V11O112−x) is continually and reversibly tunable by redox treatment.
M. Sadakane, S. Ohmura, K. Kodato, T. Fujisawa, K. Kato, K. Shimidzu, T. Murayama and W. Ueda, Chem. Commun., 2011, 47, 10812 DOI: 10.1039/C1CC13454J
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