Issue 36, 2011
From the journal:

Chemical Communications

Anodic properties of diarylethene derivatives having organometallic piano-stool tags†

Kan Wu,a   Siden Top,*b   Elizabeth A. Hillard,b   Gérard Jaouenb  and  William E. Geiger*a  

* Corresponding authors

a Department of Chemistry, University of Vermont, Burlington, USA
E-mail: william.geiger@uvm.edu

b Chimie ParisTech, Laboratoire Charles Friedel (LCF), CNRS UMR 7223, Paris, France

Abstract

The half-sandwich tamoxifen derivative, Mn(CO)3(η5-C5H4(Et)C[double bond, length as m-dash]C(C6H5)2), gives a radical cation which is charge-delocalized between the “cymantrenyl” and diphenylethene moieties and undergoes facile metal-carbonyl substitution reactions. Mn and Re complexes with finely tuned redox potentials can be obtained for cancer cell inhibition studies.

Graphical abstract: Anodic properties of diarylethene derivatives having organometallic piano-stool tags

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Article information

DOI
https://doi.org/10.1039/C1CC13787E
Article type
Communication
Submitted
24 Jun 2011
Accepted
16 Jul 2011
First published
11 Aug 2011

Chem. Commun., 2011,47, 10109-10111

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Anodic properties of diarylethene derivatives having organometallic piano-stool tags

K. Wu, S. Top, E. A. Hillard, G. Jaouen and W. E. Geiger, Chem. Commun., 2011, 47, 10109 DOI: 10.1039/C1CC13787E

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