Issue 38, 2011
From the journal:

Chemical Communications

Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet†‡

Robin J. Blagg,a   Floriana Tuna,a   Eric J. L. McInnes*a  and  Richard E. P. Winpenny*a  

* Corresponding authors

a The Lewis Magnetism Laboratory, School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, UK
E-mail: richard.winpenny@manchester.ac.uk
Tel: +44(0)161 275 4654

Abstract

Pentametallic Ln complexes of formula [Ln5O(OiPr)13] have been made, where LnIII = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.

Graphical abstract: Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

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Article information

DOI
https://doi.org/10.1039/C1CC14186D
Article type
Communication
Submitted
12 Jul 2011
Accepted
11 Aug 2011
First published
01 Sep 2011

Chem. Commun., 2011,47, 10587-10589

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Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

R. J. Blagg, F. Tuna, E. J. L. McInnes and R. E. P. Winpenny, Chem. Commun., 2011, 47, 10587 DOI: 10.1039/C1CC14186D

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